Competitive solvation of the imidazolium cation by water and methanol
نویسندگان
چکیده
منابع مشابه
Cluster structure of imidazolium salts in methanol controlled by the balance of interactions: cation-anion, cation-solvent, and anion-solvent.
We have studied the cluster structure of 1-butyl-3-methylimidazolium halide, bmimX (X = Cl, Br, I), in methanol solution by means of an electrospray mass spectrometer, which is specially designed for analysis of clusters isolated from solution. In positive ion mode experiments, the ratio of solvated bmim(+), bmim(+)(MeOH)(n) and ion-pair clusters, bmim(bmim(+)X(-))(m) was dependent on the count...
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ژورنال
عنوان ژورنال: Chemical Physics Letters
سال: 2015
ISSN: 0009-2614
DOI: 10.1016/j.cplett.2015.01.051